Tetraaquabis[2-(2,4-dichlorophenoxy)acetato]nickel(II)
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چکیده
In the title complex, [Ni(C(8)H(5)Cl(2)O(3))(2)(H(2)O)(4)], the Ni(II) atom (site symmetry ) adopts a slightly distorted NiO(6) octa-hedral coordination. An intra-molecular O-H⋯O hydrogen bond helps to establish the conformation. In the crystal, further O-H⋯O hydrogen bonds link the mol-ecules.
منابع مشابه
catena-Poly[zinc(II)-bis[μ-2-(2,4-dichlorophenoxy)acetato]]
The title polymeric compound, [Zn(C(8)H(5)Cl(2)O(3))(2)](n), was prepared by reaction of zinc(II) chloride with 2,4-dichloro-phenoxy-acetic acid and sodium hydroxide under hydro-thermal conditions. The Zn(II) atom is coordinated in a distorted tetra-hedral environment by four O atoms from four 2,4-dichloro-phenoxy-acetate ligands. Each ligand bridges two Zn(II) atoms, forming a polymeric chain ...
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The title compound, {[Cu(2)(C(8)H(5)Cl(2)O(3))(C(10)H(8)N(2))(2)]NO(3)}(n) was prepared by reacting copper(II) nitrate with 4,4'-bipyridine (4,4'-bipy) and (2,4-dichloro-phen-oxy)acetic acid under solvothermal conditions. Each of two copper(I) atoms in the asymmetric unit is three-coordinated by two N atoms from two 4,4'-bipy ligands and one O atom from the (2,4-dichloro-phen-oxy)acetate ligand...
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In the title compound, [Pd(C(11)H(9)N(2)O(4))(2)(H(2)O)(4)]·2H(2)O, the palladium(II) cation lies on an inversion centre and is hexa-coordinated by two carboxyl-ate O atoms from two (1-carboxyl-atomethyl-1,3-benzimidazol-3-ium-3-yl)acetate ligands and four water mol-ecules, with a slightly distorted octa-hedral geometry. O-H⋯O hydrogen bonds link the mol-ecules together.
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